Effect of Shale Reservoir Characteristics on Shale Oil Movability in the Lower Third Member of the Shahejie Formation,Zhanhua Sag     

NING Chuanxiang  MA Zhongliang  JIANG Zhenxue  SU Siyuan  LI Tingwei  ZHENG Lunju  WANG Guozhen  LI Fengxun 《《地质学报》英文版》2020,94(2):352-363

To reveal the effect of shale reservoir characteristics on the movability of shale oil and its action mechanism in the lower third member of the Shahejie Formation(Es3l), samples with different features were selected and analyzed using N2 adsorption, high-pressure mercury injection capillary pressure(MICP), nuclear magnetic resonance(NMR), high-speed centrifugation, and displacement image techniques. The results show that shale pore structure characteristics control shale oil movability directly. Movable oil saturation has a positive relationship with pore volume for radius > 2 μm, as larger pores often have higher movable oil saturation, indicating that movable oil is present in relatively larger pores. The main reasons for this are as follows. The relatively smaller pores often have oil-wetting properties because of organic matter, which has an unfavorable effect on the flow of oil, while the relatively larger pores are often wetted by water, which is helpful to shale oil movability. The rich surface provided by the relatively smaller pores is beneficial to the adsorption of immovable oil. Meanwhile, the relatively larger pores create significant pore volume for movable oil. Moreover, the larger pores often have good pore connectivity. Pores and fractures are interconnected to form a complex fracture network, which provides a good permeability channel for shale oil flow. The smaller pores are mostly distributed separately;thus, they are not conducive to the flow of shale oil. The mineral composition and fabric macroscopically affect the movability of shale oil. Calcite plays an active role in shale oil movability by increasing the brittleness of shale and is more likely to form micro-cracks under the same stress background. Clay does not utilize shale oil flow because of its large specific surface area and its block effect. The bedding structure increases the large-scale storage space and improves the connectivity of pores at different scales, which is conducive to the movability of shale oil.  相似文献   

日照市土壤地球化学元素分布规律及成因探讨          下载免费PDF全文

庞绪贵  宋娟娟  代杰瑞  喻超  张华平  陈磊  任天龙  王红晋 《山东国土资源》2018,34(4)

在日照市开展多目标区域地球化学调查，获取了表层土壤和深层土壤地球化学数据，通过对获得的地球化学参数进行统计分析，确定了日照市土壤地球化学基准值和背景值，认为日照市除部分元素或指标外，大部分元素或指标土壤地球化学基准值和背景值与全省土壤地球化学基准值和背景值接近。研究发现，日照市As，Cd，Cr，Cu，Hg，Ni，Pb，Zn等8种重金属元素背景值含量低于国家土壤环境质量标准的土壤一级标准限值，日照市土壤质量基本保持自然背景水平；而受工业化生产和城市化建设等后期人为活动影响，日照市表层土壤中Cd，C，Hg，N，P，S，Se，Corg等元素或指标出现明显富集，应引起重视。  相似文献   

Rare earth elements and yttrium in ferromanganese deposits from the South China Sea: distribution, composition and resource considerations     

ZHONG Yi  CHEN Zhong  GONZALEZ Francisco Javier  ZHENG Xufeng  LI Gang  LUO Yun  MO Aibin  XU Antao  WANG Shuhong 《海洋学报(英文版)》2018,37(7):41-54

Ferromanganese nodules and crusts contain relatively high concentration of rare earth elements(REE) and yttrium(REY),with a growing interest in exploitation as an alternative to land-based REY resources.On the basis of comprehensive geochemical approach,the abundance and distribution of REY in the ferromanganese nodules from the South China Sea are analyzed.The results indicate that the REY contents in ferromanganese deposits show a clear geographic regularity.Total REY contents range from 69.1×10~(–6) to 2 919.4×10~(–6),with an average value of 1 459.5×10~(–6).Especially,the enrichment rate of Ce content is high,accounting for almost 60% of the total REY.This REE enrichment is controlled mainly by the sorption of ferromanganese oxides and clay minerals in the nodules and crusts.Moreover,the total REY are higher in ferromanganese deposits of hydrogenous origin than of diagenetic origin.Finally,Light REE(LREE) and heavy REE(HREE) oxides of the ferromanganese deposits in the study area can be classified into four grades: non-enriched type,weakly enriched type,enriched type,and extremely enriched type.According to the classification criteria of rare earth resources,the Xisha and Zhongsha platform-central deep basin areas show a great potential for these rare earth metals.  相似文献   

内蒙古鲁新井田水文地质条件研究          下载免费PDF全文

赵志强  安美艳  高奎锋  王兆亮  王福芝 《山东国土资源》2018,34(6)

矿产资源开发导致了地下水失衡,地下水失衡又给矿产开发造成了极大的安全隐患,近年来,矿产资源开发与地下水环境保护之间的矛盾愈发凸显。通过对内蒙古鲁新井田典型的水文地质条件进行分析研究,分析采矿导致地下水失衡机理,深入剖析矿井开采充水条件及矿山开发对地下水环境的影响,合理提出了促进矿产开发与地下水保护相互协调的对策建议,为实现"采矿保水"协调统一提供了基础地质依据。为类似地区矿产开发过程中遵循自然规律,趋利避害,保障生产安全,保护地下水环境安全,实现资源绿色开发有较好的指导借鉴作用。  相似文献   

豫西南泥湖地区辉长岩地球化学特征及其与成矿关系          下载免费PDF全文

刘辉 《山东国土资源》2018,34(3)

豫西南泥湖钼矿集区是以花岗斑岩体为中心的钼多金属矿床系列,区内出露大面积加里东期变辉长岩和燕山期辉长岩。通过分析区内辉长岩的岩石学、年代学、地球化学和成矿元素等方面特征,研究其在成岩成矿过程中的作用。区内加里东期变辉长岩和燕山期辉长岩成矿元素总稀土含量低,稀土元素球粒陨石标准化曲线右倾平缓,具有明显的Eu,Tm元素的异常;同比世界基性岩,自晚元古代上地幔主要成矿元素(除钨元素以外)基本没有明显的富集,主成矿元素钼含量呈明显的亏损,预示燕山期成矿花岗质岩浆没有从上地幔获得主要成矿物质。初步认为大规模的钼多金属成矿带的形成与基性岩浆的底垫作用相关,基性岩浆的底垫作用为下地壳部分熔融形成岩浆房提供了热源。  相似文献   

新疆S214公路台特玛湖干涸湖盆段风沙危害及防治     

蔡东旭  李生宇  王海峰  俞祥祥  王世杰  徐新文 《中国沙漠》2020,40(1):1-11

新疆S214（考干-米兰，考米线）公路位于库鲁克塔格沙漠东南缘，穿越台特玛湖干涸湖盆。由于该区气候干旱，风力强劲，沙源丰富，流动沙丘广布且快速移动，风沙危害对公路运输构成严重威胁。通过对风沙环境和风沙危害定位观测和土壤水盐特征系统调查，确定了风沙危害极为严重的公路区段，提出了合理的风沙防护措施及防沙体系结构。结果表明：该区具有明显的单风向风况，主要盛行ENE和NE风，偶有反向风沙活动，起沙风频率、输沙势、输沙率极高，属于高能-大比率风能环境；受土壤水分、盐分含量影响，地表紧实度差异较大，部分地段为极疏松的沙层，部分地段为紧实的盐壳；S214公路风沙危害防护区段为K4+900~K18+200，设计建造的阻-固-输相结合的机械-植物复合防沙体系，防沙效果明显，保障了道路安全运营。这一强风沙、高盐区公路防沙体系建设模式可为类似环境地区工程防沙提供借鉴。  相似文献   

全球粮食安全格局的时空演化     

蔡建明  马恩朴  林静  廖柳文  韩燕 《地理学报(英文版)》2020,30(2):179-196

Food security is the primary prerequisite for achieving other Millennium Development Goals(MDGs).Given that the MDG of“halving the proportion of hungers by 2015”was not realized as scheduled,it will be more pressing and challenging to reach the goal of zero hunger by 2030.So there is high urgency to find the pattern and mechanism of global food security from the perspective of spatio-temporal evolution.In this paper,based on the analysis of database by using a multi-index evaluation method and radar map area model,the global food security level for 172 countries from 2000 to 2014 were assessed;and then spatial autocorrelation analysis was conducted to depict the spatial patterns and changing characteristics of global food security;then,multi-nonlinear regression methods were employed to identify the factors affecting the food security patterns.The results show:1)The global food security pattern can be summarized as“high-high aggregation,low-low aggregation”.The most secure countries are mainly distributed in Western Europe,North America,Oceania and parts of East Asia.The least secure countries are mainly distributed in sub-Saharan Africa,South Asia and West Asia,and parts of Southeast Asia.2)Europe and sub-Saharan Africa are hot and cold spots of the global food security pattern respectively,while in non-aggregation areas,Haiti,North Korea,Tajikistan and Afghanistan have long-historical food insecurity problems.3)The pattern of global food security is generally stable,but the internal fluctuations in the extremely insecure groups were significant.The countries with the highest food insecurity are also the countries with the most fluctuated levels of food security.4)The annual average temperature,per capita GDP,proportion of people accessible to clean water,political stability and non-violence levels are the main factors influencing the global food security pattern.Research shows that the status of global food security has improved since the year 2000,yet there are still many challenges such as unstable global food security and acute regional food security issues.It will be difficult to understand these differences from a single factor,especially the annual average temperature and annual precipitation.The abnormal performance of the above factors indicates that appropriate natural conditions alone do not absolutely guarantee food security,while the levels of agricultural development,the purchasing power of residents,regional accessibility,as well as political and economic stability have more direct influence.  相似文献   

象山港海域分区评价方法研究          下载免费PDF全文

金余娣  叶林安  刘莲  章紫宁  鲁水 《海洋开发与管理》2020,37(7):45-48

文章根据2011-2018年在象山港海域调查的象山港水文、水团、水环境、沉积物环境、生物生态等调查数据，将象山港海域划分为若干个具有不同生态变化特征的区域，研究象山港海域内的空间异质性，以便剖析各区域环境的问题。研究发现：象山港水交换特征、水团分布、水环境、沉积环境和生物生态特征将象山港划分为A、B、C、D、E 5个区评价较为合理。该方法可以有效并合理地对象山港海域做出评价，并为相关海洋科学工作者和管理者提供科学依据。  相似文献   

First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

珠江口黄茅海底质沉积中介形类的生态类型及其分布特征          下载免费PDF全文

黄毅  吴洁  殷征欣  关瑶  倪锦锋 《海洋开发与管理》2020,37(6):89-94

文章通过对黄茅海底质沉积样品中的介形类生态类型进行研究，探讨其空间分布特征。研究结果显示：研究区内出现的介形类可划分为4种生态类型，总体表现为以近岸广盐型分子占主导地位，优势度极高；浅海多盐 真盐型分子次之；而广海真盐型和淡水 微盐型分子丰度很低。根据黄茅海河口湾的水体条件，可大致将研究区划分为5种亚环境区，各区内的介形类生态类型组成也存在较大差别，表现出不同的空间分布特征。介形类分布受海水盐度控制最大，其次为水动力条件。在水体盐度小、水动力条件强的河流入海口及其影响区域，介形类丰度小，且生态类型单一；而在黄茅海河口湾南部海域，由于海水底层盐度全年在15‰以上，水动力条件适宜，介形类丰度总体较高，生态类型增多。  相似文献